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  1. AI‐Driven Robot Enables Synthesis‐Property Relation Prediction for Metal Halide Perovskites in Humid Atmosphere

    Abstract Materials Acceleration Platforms (MAPs) – also known as self‐driving laboratories– present a new paradigm for materials science and promise an order of magnitude accelerated materials discovery compared to the traditional trial‐and‐error approach. Metal halide perovskites (MHPs) are an emerging class of materials for optoelectronic applications but are plagued by irreproducible optoelectronic quality, particularly for films fabricated in a humid atmosphere. Here, a machine learning (ML)‐guided closed‐loop platform is developed with a multimodal data fusion approach to predict synthesis–property relations for the optical quality of MHP thin films in relative humidities (RHs) ranging from 5–55%. The efficiency of this approachmore » is confirmed by the fast‐dropping learning rate to 2% after experimentally sampling less than 1% of the possible 5,000+ combinations. The prediction of synthesis–property relations is done by optical and imaging characterizations. In situ photoluminescence characterization revealed the origin of thin film quality variation at different RH. These insights provide an avenue for controlling the MHP crystallization by fine‐tuning the synthesis parameters and RH for a given chemistry, thus lifting the need for stringent atmosphere control. The MAP enables an accelerated screening and understanding of the synthesis design space, facilitating rational synthesis recipe choice for a wide range of materials.« less
  2. Measurement of differential ZZ + jets production cross sections in pp collisions at $$ \sqrt{s} $$ = 13 TeV

    Diboson production in association with jets is studied in the fully leptonic final states, pp → (Z/γ$$^{*}$$)(Z/γ$$^{*}$$) + jets → 2ℓ2ℓ′ + jets, (ℓ, ℓ′ = e or μ) in proton-proton collisions at a center-of-mass energy of 13 TeV. The data sample corresponds to an integrated luminosity of 138 fb$$^{−1}$$ collected with the CMS detector at the LHC. Differential distributions and normalized differential cross sections are measured as a function of jet multiplicity, transverse momentum p$$_{T}$$, pseudorapidity η, invariant mass and ∆η of the highest-p$$_{T}$$ and second-highest-p$$_{T}$$ jets, and as a function of invariant mass of the four-lepton system formore » events with various jet multiplicities. These differential cross sections are compared with theoretical predictions that mostly agree with the experimental data. However, in a few regions we observe discrepancies between the predicted and measured values. Further improvement of the predictions is required to describe the ZZ+jets production in the whole phase space.« less
  3. Observation of the $$\Lambda_\text{b}^0\to J/\psi\Xi^-K^+$$ decay

    Using proton–proton collision data corresponding to an integrated luminosity of $$140\hbox { fb}^{-1}$$ collected by the CMS experiment at $$\sqrt{s}= 13\,\text {Te}\hspace{-.08em}\text {V} $$, the $${{{\Lambda }} _{\text {b}}^{{0}}} \rightarrow {{\text {J}/\uppsi }} {{{\Xi }} ^{{-}}} {{\text {K}} ^{{+}}} $$ decay is observed for the first time, with a statistical significance exceeding 5 standard deviations. The relative branching fraction, with respect to the $${{{\Lambda }} _{\text {b}}^{{0}}} \rightarrow {{{\uppsi }} ({2\textrm{S}})} {{\Lambda }} $$ decay, is measured to be $$\mathcal {B}({{{\Lambda }} _{\text {b}}^{{0}}} \rightarrow {{\text {J}/\uppsi }} {{{\Xi }} ^{{-}}} {{\text {K}} ^{{+}}} )/\mathcal {B}({{{\Lambda }} _{\text {b}}^{{0}}} \rightarrowmore » {{{\uppsi }} ({2\textrm{S}})} {{\Lambda }} ) = [3.38\pm 1.02\pm 0.61\pm 0.03]\%$$, where the first uncertainty is statistical, the second is systematic, and the third is related to the uncertainties in $$\mathcal {B}({{{\uppsi }} ({2\textrm{S}})} \rightarrow {{\text {J}/\uppsi }} {{{\uppi }} ^{{+}}} {{{\uppi }} ^{{-}}} )$$ and $$\mathcal {B}({{{\Xi }} ^{{-}}} \rightarrow {{\Lambda }} {{{\uppi }} ^{{-}}} )$$.« less
  4. Search for Higgs boson pair production with one associated vector boson in proton-proton collisions at $$ \sqrt{s} $$ = 13 TeV

    A search for Higgs boson pair (HH) production in association with a vector boson V (W or Z boson) is presented. The search is based on proton-proton collision data at a center-of-mass energy of 13 TeV, collected with the CMS detector at the LHC, corresponding to an integrated luminosity of 138 fb$$^{−1}$$. Both hadronic and leptonic decays of V bosons are used. The leptons considered are electrons, muons, and neutrinos. The HH production is searched for in the $$ \textrm{b}\overline{\textrm{b}}\textrm{b}\overline{\textrm{b}} $$ decay channel. An observed (expected) upper limit at 95% confidence level of VHH production cross section is set atmore » 294 (124) times the standard model prediction. Constraints are also set on the modifiers of the Higgs boson trilinear self-coupling, k$$_{λ}$$, assuming k$$_{2V}$$ = 1, and vice versa on the coupling of two Higgs bosons with two vector bosons, k$$_{2V}$$. The observed (expected) 95% confidence intervals of these coupling modifiers are −37.7 < k$$_{λ}$$ < 37.2 (−30.1 < k$$_{λ}$$ < 28.9) and −12.2 < k$$_{2V}$$ < 13.5 (−7.2 < k$$_{2V}$$ < 8.9), respectively.[graphic not available: see fulltext]« less
  5. Performance of the CMS electromagnetic calorimeter in pp collisions at √$$_{s}$$ = 13 TeV

    The operation and performance of the Compact Muon Solenoid(CMS) electromagnetic calorimeter (ECAL) are presented, based ondata collected in pp collisions at√$$_{s}$$ =13 TeV at the CERN LHC, in the years from 2015 to 2018(LHC Run 2), corresponding to an integrated luminosity of151 fb$$^{-1}$$. The CMS ECAL is a scintillating lead-tungstatecrystal calorimeter, with a silicon strip preshower detector in theforward region that provides precise measurements of the energy andthe time-of-arrival of electrons and photons. The successfuloperation of the ECAL is crucial for a broad range of physics goals,ranging from observing the Higgs boson and measuring its properties,to other standard model measurements andmore » searches for newphenomena. Precise calibration, alignment, and monitoring of theECAL response are important ingredients to achieve these goals. Toface the challenges posed by the higher luminosity, whichcharacterized the operation of the LHC in Run 2, the proceduresestablished during the 2011–2012 run of the LHC have been revisitedand new methods have been developed for the energy measurement andfor the ECAL calibration. The energy resolution of the calorimeter,for electrons from Z boson decays reaching theECAL without significant loss of energy by bremsstrahlung, wasbetter than 1.8%, 3.0%, and 4.5% in the |η| intervals[0.0,0.8], [0.8,1.5], [1.5, 2.5], respectively. This resultingperformance is similar to that achieved during Run 1 in 2011–2012,in spite of the more severe running conditions.« less
  6. Search for Higgs boson pair production in the $$ \textrm{b}\overline{\textrm{b}}{\textrm{W}}^{+}{\textrm{W}}^{-} $$ decay mode in proton-proton collisions at $$ \sqrt{s} $$ = 13 TeV

    A search for Higgs boson pair (HH) production with one Higgs boson decaying to two bottom quarks and the other to two W bosons are presented. The search is done using proton-proton collisions data at a centre-of-mass energy of 13 TeV, corresponding to an integrated luminosity of 138 fb$$^{−1}$$ recorded by the CMS detector at the LHC from 2016 to 2018. The final states considered include at least one leptonically decaying W boson. No evidence for the presence of a signal is observed and corresponding upper limits on the HH production cross section are derived. The limit on the inclusivemore » cross section of the nonresonant HH production, assuming that the distributions of kinematic observables are as expected in the standard model (SM), is observed (expected) to be 14 (18) times the value predicted by the SM, at 95% confidence level. The limits on the cross section are also presented as functions of various Higgs boson coupling modifiers, and anomalous Higgs boson coupling scenarios. In addition, limits are set on the resonant HH production via spin-0 and spin-2 resonances within the mass range 250–900 GeV.[graphic not available: see fulltext]« less
  7. Search for a scalar or pseudoscalar dilepton resonance produced in association with a massive vector boson or top quark-antiquark pair in multilepton events at s =13TeV

    A search for beyond the standard model spin-0 bosons, ϕ , that decay into pairs of electrons, muons, or tau leptons is presented. The search targets the associated production of such bosons with a W or Z gauge boson, or a top quark-antiquark pair, and uses events with three or four charged leptons, including hadronically decaying tau leptons. The proton-proton collision data set used in the analysis was collected at the LHC from 2016 to 2018 at a center-of-mass energy of 13 TeV, and corresponds to an integrated luminosity of 138fb - 1 more » . The observations are consistent with the predictions from standard model processes. Upper limits are placed on the product of cross sections and branching fractions of such new particles over the mass range of 15 to 350 GeV with scalar, pseudoscalar, or Higgs-boson-like couplings, as well as on the product of coupling parameters and branching fractions. Several model-dependent exclusion limits are also presented. For a Higgs-boson-like ϕ model, limits are set on the mixing angle of the Higgs boson with the ϕ boson. For the associated production of a ϕ boson with a top quark-antiquark pair, limits are set on the coupling to top quarks. Finally, limits are set for the first time on a fermiophilic dilaton-like model with scalar couplings and a fermiophilic axion-like model with pseudoscalar couplings.« less
  8. Evidence for tWZ production in proton-proton collisions at s =13 TeV in multilepton final states

    The first evidence for the standard model production of a top quark in association with a W boson and a Z boson is reported. The measurement is performed in multilepton final states, where the Z boson is reconstructed via its decays to electron or muon pairs. At least one W boson, associated or from top quark decay, decays leptonically, too. The analysed data were recorded by the CMS experiment at the CERN LHC in 2016–2018 in proton-proton collisions at s =13 TeV, and correspond to an integrated luminosity of 138 fb−1. The measured crossmore » section is 354±54(stat)±95(syst) fb, and corresponds to a statistical significance of 3.4 standard deviations.« less
  9. Search for stealth supersymmetry in final states with two photons, jets, and low missing transverse momentum in proton-proton collisions at s =13TeV

    The results of a search for stealth supersymmetry in final states with two photons and jets, targeting a phase space region with low missing transverse momentum ( p T miss ), are reported. The study is based on a sample of proton-proton collisions at s = 13 TeV collected by the CMS experiment, corresponding to an integrated luminosity of 138fb - 1 . As LHC results continue to constrain the parameter spacemore » of the minimal supersymmetric standard model, the low p T miss regime is increasingly valuable to explore. To estimate the backgrounds due to standard model processes in such events, we apply corrections derived from simulation to an estimate based on a control selection in data. The results are interpreted in the context of simplified stealth supersymmetry models with gluino and squark pair production. The observed data are consistent with the standard model predictions, and gluino (squark) masses of up to 2150 (1850) GeV are excluded at the 95% confidence level.« less
  10. Search for a third-generation leptoquark coupled to a τ lepton and a b quark through single, pair, and nonresonant production in proton-proton collisions at $$ \sqrt{s} $$ = 13 TeV

    A search is presented for a third-generation leptoquark (LQ) coupled exclusively to a τ lepton and a b quark. The search is based on proton-proton collision data at a center-of-mass energy of 13 TeV recorded with the CMS detector, corresponding to an integrated luminosity of 138 fb$$^{−1}$$. Events with τ leptons and a varying number of jets originating from b quarks are considered, targeting the single and pair production of LQs, as well as nonresonant t-channel LQ exchange. An excess is observed in the data with respect to the background expectation in the combined analysis of all search regions. Formore » a benchmark LQ mass of 2 TeV and an LQ-b-τ coupling strength of 2.5, the excess reaches a local significance of up to 2.8 standard deviations. Upper limits at the 95% confidence level are placed on the LQ production cross section in the LQ mass range 0.5–2.3 TeV, and up to 3 TeV for t-channel LQ exchange. Leptoquarks are excluded below masses of 1.22–1.88 TeV for different LQ models and varying coupling strengths up to 2.5. The study of nonresonant ττ production through t-channel LQ exchange allows lower limits on the LQ mass of up to 2.3 TeV to be obtained.[graphic not available: see fulltext]« less
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